In this problem, submit one pa

In this problem, submit one part at a time, and use the givenfeedback to answer subsequent parts.

100. mL of aqueous 0.40 M CuSO4 is mixed with 100. mL ofaqueous 0.20 M Na2S.

a. What kind of reaction could potentially takeplace?

-Bronsted-Lowry acid-base

-no reaction correct

-precipitation

-redox

b. Which of the following is a spectator ion in thismixture? The table at the bottom may be useful.(Select all thatapply.)

– Na+

-SO42-

– S2-

-Cu2+

c. After the solutions are mixed, what will be theconcentration of Na+?

-0.80 M

-0.10 M

-0.40 M

-0.20 M

d. After the solutions are mixed, what will be theconcentration of SO42-?

-0.10 M

-0.80 M

-0.20 M

-0.40 M

e. Which reactant will limit the amount of product thatcan form?

-something else

-Cu2+

-S2-

f. This mixture will establish equilibrium in merefractions of a second. After it does, what will be theconcentration of Cu2+?

-0.20 M

-zero M

-0.40 M

-something much smaller than 0.10 M

-0.10 M

g. This mixture will establish equilibrium in merefractions of a second. After it does, what will be theconcentration of S2-? M

Answer:

100. mL of aqueous 0.40 M CuSO4 is mixed with 100. mL ofaqueous 0.20 M Na2S.

Note that Cu2+ and S-2 are present, they will form CuS(s) sinceCuS is not that soluble

a. What kind of reaction could potentially takeplace?

-precipitation

b. Which of the following is a spectator ion in thismixture? The table at the bottom may be useful.(Select all thatapply.)

spectator ion are those which will NOT form any kind ofprecipitate, therefore, they are SO4-2 and Na2+ ions, since Na2SO4is soluble

c. After the solutions are mixed, what will be theconcentration of Na+?

[Na+] = M1*V1/(V1+V2) = 0.4*100/(100+100) = 0.2 M (halved)

d. After the solutions are mixed, what will be theconcentration of SO42-?

[SO4-2] = M2*V2/(V1+V2) = 0.4*100/(100+100) = 0.2 M (halved)

e. Which reactant will limit the amount of product thatcan form?

mmol of CusO4 = 40

mmol of Na2S = 100*0.2 = 20

then,

ratio is 1;1 so S-2 is limiting reaciton

f. This mixture will establish equilibrium in merefractions of a second. After it does, what will be theconcentration of Cu2+?

[Cu2+] = 40 mmol – 20 mmol reacted = 20 mmol left

Vtotal = 100+100 = 200 mL

[Cu2+] = 20/200 = 0.1 M

g. This mixture will establish equilibrium in merefractions of a second. After it does, what will be theconcentration of S2-? M

the concentration will be mostly zero, since CuS <-> Cu2+S-2 solbuiltiy is too low


 
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